Biogeochemistry of dissolved carbon,major, and trace elements during spring flood periods on the Ob River

Detailed knowledge of the flood period of Arctic rivers remains one of the few factors impeding rigorous prediction of the effect of climate change on carbon and related element fluxes from the land to the Arctic Ocean. In order to test the temporal and spatial variability of element concentration in the Ob River (western Siberia) water during flood period and to quantify the contribution of spring flood period to the annual element export, we sampled the main channel year round in 2014–2017 for dissolved C, major, and trace element concentrations. We revealed high stability (approximately ≤10% relative variation) of dissolved C, major, and trace element concentrations in the Ob River during spring flood period over a 1‐km section of the river channel and over 3 days continuous monitoring (3‐hr frequency). We identified two groups of elements with contrasting relationship to discharge: (a) DIC and soluble elements (Cl, SO₄, Li, B, Na, Mg, Ca, P, V, Cr, Mn, As, Rb, Sr, Mo, Ba, W, and U) negatively correlated (p < 0.05) with discharge and exhibited minimal concentrations during spring flood and autumn high flow and (b) DOC and particle‐reactive elements (Al, Fe, Ti, Y, Zr, Nb, Cs, REEs, Hf, Tl, Pb, and Th), some nutrients (K), and metalloids (Ge, Sb, and Te), positively correlated (p < 0.05) with discharge and showed the highest concentrations during spring flood. We attribute the decreased concentration of soluble elements with discharge to dilution by groundwater feeding and increased concentration of DOC and particle‐reactive metals with discharge to leaching from surface soil, plant litter, and suspended particles. Overall, the present study provides first‐order assessment of fluxes of major and trace elements in the middle course of the Ob River, reveals their high temporal and spatial stability, and characterizes the mechanism of river water chemical composition acquisition.     

Dynamics of hourly sea level at Hillarys Boat Harbour,Western Australia: a chaos theory perspective

Water level forecasting using recorded time series can provide a local modelling capability to facilitate local proactive management practices. To this end, hourly sea water level time series are investigated. The records collected at the Hillarys Boat Harbour, Western Australia, are investigated over the period of 2000 and 2002. Two modelling techniques are employed: low-dimensional dynamic model, known as the deterministic chaos theory, and genetic programming, GP. The phase space, which describes the evolution of the behaviour of a nonlinear system in time, was reconstructed using the delay-embedding theorem suggested by Takens. The presence of chaotic signals in the data was identified by the phase space reconstruction and correlation dimension methods, and also the predictability into the future was calculated by the largest Lyapunov exponent to be 437 h or 18 days into the future. The intercomparison of results of the local prediction and GP models shows that for this site-specific dataset, the local prediction model has a slight edge over GP. However, rather than recommending one technique over another, the paper promotes a pluralistic modelling culture, whereby different techniques should be tested to gain a specific insight from each of the models. This would enable a consensus to be drawn from a set of results rather than ignoring the individual insights provided by each model.     

Radionuclides and mercury in the salt lakes of the Crimea

90 Sr concentrations,resulting from the Chernobyl NPP accident,were determined in the salt lakes of the Crimea(Lakes Kiyatskoe,Kirleutskoe,Kizil-Yar,Bakalskoe and Donuzlav),together with the redistribution between the components of the ecosystems.The content of mercury in the waters of the studied reservoirs was also established.Vertical distributions of natural radionuclide activities( 238 U,232 Th,226 Ra,210 Pb,40 K) and anthropogenic 137 Cs concentrations(as radiotracers) were determined in the bottom sediments of the Koyashskoe salt lake(located in the south-eastern Crimea) to evaluate the longterm dynamics and biogeochemical processes.Radiochemical and chemical analysis was undertaken and radiotracer and statistical methods were applied to the analytical data.The highest concentrations of 90 Sr in the water of Lake Kiyatskoe(350.5 and 98.0 Bq/m 3) and Lake Kirleutskoe(121.3 Bq/m 3) were due to the discharge of the Dnieper water from the North-Crimean Canal.The high content of mercury in Lake Kiyatskoe(363.2 ng/L) and in seawater near Lake Kizil-Yar(364 ng/L) exceeded the maximum permissible concentration(3.5 times the maximum).Natural radionuclides provide the main contribution to the total radioactivity(artificial and natural combined) in the bottom sediments of Lake Koyashskoe.The significant concentration of 210 Pb in the upper layer of bottom sediments of the lake indicates an active inflow of its parent radionuclide—gaseous 222 Rn from the lower layers of the bottom sediment.The average sedimentation rates in Lake Koyashskoe,determined using 210 Pb and 137 Cs data,were 0.117 and 0.109 cm per year,respectively.     

Numerical study on transient harbor oscillations induced by successive solitary waves

Tsunamis are traveling waves which are characterized by long wavelengths and large amplitudes close to the shore. Due to the transformation of tsunamis, undular bores have been frequently observed in the coastal zone and can be viewed as a sequence of solitary waves with different wave heights and different separation distances among them. In this article, transient harbor oscillations induced by incident successive solitary waves are first investigated. The transient oscillations are simulated by a fully nonlinear Boussinesq model, FUNWAVE-TVD. The incident successive solitary waves include double solitary waves and triple solitary waves. This paper mainly focuses on the effects of different waveform parameters of the incident successive solitary waves on the relative wave energy distribution inside the harbor. These wave parameters include the incident wave height, the relative separation distance between adjacent crests, and the number of elementary solitary waves in the incident wave train. The relative separation distance between adjacent crests is defined as the ratio of the distance between adjacent crests in the incident wave train to the effective wavelength of the single solitary wave. Maximum oscillations inside the harbor excited by various incident waves are also discussed. For comparison, the transient oscillation excited by the single solitary wave is also considered. The harbor used in this paper is assumed to be long and narrow and has constant depth; the free surface movement inside the harbor is essentially one-dimensional. This study reveals that, for the given harbor and for the variation ranges of all the waveform parameters of the incident successive solitary waves studied in this paper, the larger incident wave heights and the smaller number of elementary solitary waves in the incident tsunami lead to a more uniform relative wave energy distribution inside the harbor. For the successive solitary waves, the larger relative separation distance between adjacent crests can cause more obvious fluctuations of the relative wave energy distribution over different resonant modes. When the wave height of the elementary solitary wave in the successive solitary waves equals to that of the single solitary wave and the relative separation distance between adjacent crests is equal to or greater than 0.6, the maximum oscillation inside the harbor induced by the successive solitary waves is almost identical to that excited by the single solitary wave.     

Geochemical and microbiological characteristics of sediments near the Malenky mud volcano (Lake Baikal, Russia), with evidence of Archaea intermediate between the marine anaerobic methanotrophs ANME-2 and ANME-3

Detailed lithological, biogeochemical and molecular biological analyses of core sediments collected in 2002–2006 from the vicinity of the Malenky mud volcano, Lake Baikal, reveal considerable spatial variations in pore water chemical composition, with total concentrations of dissolved salts varying from 0.1 to 1.8‰. Values of methane δ¹³С in the sediments suggest a biogenic origin (δ¹³С_min. ?61.3‰, δ¹³С_max. ?72.9‰). Rates of sulphate reduction varied from 0.001 to 0.7 nmol cm^?3 day^?1, of autotrophic methanogenesis from 0.01 to 2.98 nmol CH₄ cm^?3 day^?1, and of anaerobic oxidation of methane from 0 to 12.3 nmol cm^?3 day^?1. These results indicate that methanogenic processes dominate in gas hydrate-bearing sediments of Lake Baikal. Based on clone libraries of 16S rRNA genes amplified with Bacteria- and Archaea-specific primers, investigation of microbial diversity in gas hydrate-bearing sediments revealed bacterial 16S rRNA clones classified as Deltaproteobacteria, Gammaproteobacteria, Chloroflexi and OP11. Archaeal clone sequences are related to the Crenarchaeota and Euryarchaeota. Baikal sequences of Archaea form a distinct cluster occupying an intermediate position between the marine groups ANME-2 and ANME-3 of anaerobic methanotrophs.     

Molecular and isotopic characteristics of gas hydrate-bound hydrocarbons in southern and central Lake Baikal

We investigated the molecular composition (methane, ethane, and propane) and stable isotope composition (methane and ethane) of hydrate-bound gas in sediments of Lake Baikal. Hydrate-bearing sediment cores were retrieved from eight gas seep sites, located in the southern and central Baikal basins. Empirical classification of the methane stable isotopes (δ¹³C and δD) for all the seep sites indicated the dominant microbial origin of methane via methyl-type fermentation; however, a mixture of thermogenic and microbial gases resulted in relatively high methane δ¹³C signatures at two sites where ethane δ¹³C indicated a typical thermogenic origin. At one of the sites in the southern Baikal basin, we found gas hydrates of enclathrated microbial ethane in which ¹³C and deuterium were both highly depleted (mean δ¹³C and δD of –61.6‰ V-PDB and –285.4‰ V-SMOW, respectively). To the best of our knowledge, this is the first report of C₂ δ¹³C–δD classification for hydrate-bound gas in either freshwater or marine environments.     

Coastal Upwelling Activity on the Pacific Shelf of the Baja California Peninsula

High primary productivity on the Pacific coast of the Baja California Peninsula is usually related to coastal upwelling activity that injects nutrients into the euphotic zone in response to prevailing longshore winds (from the northwest to north). The upwelling process has maximum intensity from April to June, with the coastal upwelling index varying from 50 to 300 m³/s per 100 m of coastline. Along the entire coast of the peninsula, the upwelling intensity changes in accordance with local wind conditions and bottom topography. Spatial variability can also be modulated by the influence of mesoscale meanders of the California Current. We have identified the seasonal and synoptic variability of upwelling signatures on the Baja California shelf, using averaged monthly and weekly sea surface temperature (SST) distributions obtained from remote sensing imagery from the Advanced Very High Resolution Radiometer in the period from 1996 to 2001. Analysis of SST distribution and direct experimental data on temperature and nutrient concentration shows that the areas with the coldest SST anomalies were closely related to the bottom slope, shelf width, and coastline orientation relating to wind direction. We also assume that the nutrient transport into the coastal lagoons may be forced by the coupling of coastal upwelling and tidal pumping of surface waters into the lagoon system. This revised version was published online in August 2006 with corrections to the Cover Date.     

Authigenic rhodochrosite from a gas hydrate-bearing structure in Lake Baikal

International Journal of Earth Sciences - Early diagenetic carbonates are rare in Lake Baikal. Siderite (Fe carbonate) concretions in the sediments were discovered only recently. Here, we discuss...     

Ziminaite,Fe3+VO4, a new howardevansite-group mineral from the Bezymyannyi volcano,Kamchatka, Russia

Mineralogy and Petrology - The new mineral ziminaite, ideally Fe3+VO4, was found in fumarole sublimates at the Bezymyannyi volcano, Kamchatka, Russia. Ziminaite occurs as lamellar, tabular or...     

Melt Pockets in Garnet Megacrysts from Cenozoic Alkali Basalts of the Shavaryn Tsaram Vicinity, Mongolia

Garnet megacryst with a multiphase inclusion from intraplate alkali basalts of the Shavaryn Tsaram(Tariat,Mongolia)was the object of the study.This unusual aggregate consists of porous glass,Ti-rich biotite,orthopyroxene,spinel,clinopyroxene,olivine,and ilmenite.Win TWQ 2.32 thermodynamic simulation of this system revealed a few intervals of equilibrium.Pressure and temperature adjustment reflected in the paragenetic minerals of the melt pocket.The capture of already crystallised garnet megacryst was at P=0.8-1 GPa and T=1120-1160℃.Mineral crystallisation inside the melt pocket,accompanied by external inputs,occurred at P=0.75-0.95 GPa;T=790-1120℃.Symplectite assemblage formed in the garnet megacryst due to decomposition at(P=0.55-0.7 GPa;T=850-930℃).The study of the oxygen isotope content in primary garnet and biotite of the melt pocket showed that the δ¹⁸O_VSMOW values are the same and correspond to that of typical mantle xenoliths.However,the chemical and microcomponent composition of the melt pocket minerals reveals a material that differs from basalts and peridotites.Thus,it has been revealed that the multiphase inclusion in the garnet megacryst formed not only on account of the garnet’s substance,but also due to the entrapped material of the Earth’s interior.